Referring to:
https://thwack.solarwinds.com/product-forums/server-application-monitor-sam/f/forum/53379/which-ip-to-use-during-agents-installation-in-case-of-ha
Further information on Agents:
1) When you install initially, you supply any host/ip that allows the initial connection of Agent to Orion. During the connection the Agent downloads provisioning info that contains all hosts/ips under which Orion server is known (or in HA case any of the Orion servers in the said pool)
2) During regular operation Agent uses this set of hosts/ips and tries to maintain connection to any that works for the particular agent (remember it can be in a completely different subnet than Orion)
the set of orion hosts/ips is updated when necessary while the active connection is up