Administrator Guide SolarWinds Orion

No, but that's an interesting idea. Are you looking to provide the information in more focused, condensed form as a working script, or to make something customized to your organization's standards and workflows?

So I created something similar to an administrator's guide to maintaining a clients environment. 

The key areas I focused on were;

SolarWinds Orion Basics
Introduction to SolarWinds Orion Platform
Log in to the Orion Web Console
Browser Requirements
Pre-Requisites for logging into SolarWinds
SolarWinds Website Login
Navigate Web Console
Environment
Server & IP List (per environment)
Load Balancer
Active Directory Connectivity
User Accounts
Error Log Locations
SQL Configuration
SQL Service Accounts
SQL Server Agent Jobs
Normal Operation
Failover to Secondary Site
Restore back to Primary Site
Scheduled Tasks
Software Version Information
User Access
Add Individual User Account
Delete Individual User Account
Add AD Security Group
Delete AD Security Group
Reporting
Run an Ad-Hoc Report
Run a Scheduled Report
Create a Report
Delete a Report
Import/Export of Reports
Module Specific Reports
Alerts
Create an Alert
Delete an Alert
Enable and disable alerts
Action types
Import/Export of Alerts
Import/Export of Alerts
Events
View the Event Monitor
Filtering Displayed Event Logs
View node-specific events
Dashboards
Create a Classic Dashboard
Create a Modern Dashboard
Delete a Dashboard
Performance Analysis (PerfStack) Dashboard
Health Check
Reboot Sequence
Shutdown
Restart
Upgrade
SolarWinds Upgrade
Pre-stage installation files (optional)
Pre-stage files in an online environment
Pre-stage installation files in an offline environment
Upgrade your Orion deployment
Windows Server Updates
Troubleshooting
Retrieving Logging Diagnostics
Collecting diagnostics
Stop / Restart of SolarWinds Services
Disaster Recovery
High Availability Failover
Customisations
Licensing
LDAP Authentication
Active Directory Group Setup
Dashboard
System Integrations
Active Directory Integration
Integration specific
Custom Properties Fields
Network Discovery
SQL Service AD Account
Backup Server VM and files
Restore Server VM and files from Backup Point
Further Help

Hope this helps.