Can NPM Map a workstation interface to the switchport where its connected?
Unless you are monitoring the workstation and switch, Network Performance cannot.
You would need User Device Tracker, it would only need the access switch and can report the MAC Address, IP Address, and Hostname of the workstation.
Both the switch and workstations are being monitored. Where would i be able to see the relationship.
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The NPM Network Topology Resource on the Node Details page will show all connections from device to device and Interface to Interface. Network Atlas can also show connections through Connect Now.
I have a guide working through Network Topology issues for Network Performance Monitor's Connect Now Troubleshooting Topology Issues