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I personally have found the admin guide PDFs to be indispensable for a decent amount of issues in the past. However, most of the "good info" for SolarWinds comes from Thwack and the occasionally well-worded Google query.
Unless you were more referring to a knowledge base for those who would use the app- in that case, as individual monitors and alerts, you can use the combination of built-in monitor descriptions and Custom Properties for things like directing users as to what to do when they see an alert for this Node or Component/Application (whom to call, what to try restarting, etc).
Sorry, the question was just a bit on the ambiguous side so I figured I'd answer it both ways that I read it.
Oh Thanks for the information , its actually a bit of both