Is there any way to detect and monitor this second instance (new PID #)? Thanks.
All instances of a processes that match the process name as defined in the component monitor are monitored by default. If for example you create a process monitor for notepad.exe and you have three instances of notepad running on the server, all three will be monitored in SAM with no additional configuration. You can then define a trigger condition in the Advanced Alert Manager based on Process Instance Count as needed.